Here's another Lone Ranger solo story, this one from season 1 of the first animated series.
Tiny Tom (Dick Beals) escapes from prison, but his attempts at avenging himself on the Ranger (Michael Rye) are, amazingly, as futile as the Toyman vs. Superman.
Here's "Terror in Toyland".
I doubt that kids would've noticed that Beals was also the voice of Buzz Conroy, creator and sidekick to Frankenstein, Jr. on the same network (CBS). Tiny Tom was the closest thing the Ranger had to a recurring villain.